All of Nature’s splendour seems to be reflected in the manifold opulence of fine Opals: fire and lightnings, all the colours of the rainbow and the soft shine of far seas. Australia is the classical country of origin. Almost ninety-five per cent of all fine opals come from the dry and remote outback deserts.
Numerous legends and tales surround this colourful gemstone, which can be traced back in its origins to a time long before our memory, to the ancient dream time of the Australian aborigines. It is reported in their legends that the creator came down to Earth on a rainbow, in order to bring the message of peace to all the humans. And at the very spot, where his foot touched the ground, the stones became alive and started sparkling in all the colours of the rainbow. That was the birth of the Opals.
The group of fine Opals includes quite a number of wonderful gemstones, which share one characteristic: they shine and sparkle in a continually changing play of colours full of fantasy, which experts describe as “opalising”. Depending on the kind, place of occurrence, and colour of the main body, we differentiate Dark or Black Opal, White or Light Opal, Milk or Crystal Opal, Boulder Opal, Opal Matrix, Yowah Nuts from Queensland – the so-called “picture stones“, and also Mexican and Fire Opal. Opal variations are practically unlimited. They all show in their own special way that unique play of colours – except for Fire Opal, which due to its transparency, however, is nevertheless also considered a Fine Opal specimen. If Opals are lacking the typical play of colours, they are simply named “Common Opal”.
The name Opal was probably derived from Sanskrit “upala“, meaning ”valuable stone“. This was probably the root for the Greek term “opallios”, which translates as “colour change”. In the days of Roman antiquity there existed a so-called “opalus”, or a “stone from several elements”. So the ancient Romans may already have had an inkling why the Opals show such a striking play of colours. But we will come to this later …
Pliny, the famous Roman author, called Opal a gemstone which combines the best possible characteristics of the most beautiful of gemstones: the fine sparkle of Almandine, the shining purple of Amethyst, the golden yellow of Topaz, and the deep blue of Sapphire, ”so that all colours shine and sparkle together in a beautiful combination“.
Up to the first half of the 19th century, Opals were relatively rare. But then their career boomed suddenly and made them one of the most popular gemstones, and the start of this development brought them to the gemstone cutters of the gemstone centre of Idar-Oberstein. In the era of Art Deco the Opals experienced their flourishing, with contemporary gemstone artists preferring them to all other stones because of their subdued charm, which in turn was excellently suited to be combined with enamel, another very popular material of those days.
Opal’s colour play emanates a very special attraction and fascination. But what causes this phenomenon? This question was impossible to answer for a very long time. Only when in the 1960s a team of Australian scientists analysed Opals with an electron microscope, it was discovered that small spheres from silica gel caused interference and refraction manifestations, which are responsible for the fantastic play of colours. The spheres, which are arranged in more or less compact structures, succeed in dissecting the light on its passage through the gemstone and turning it into all the colours of the rainbow, always new and always different.
Australia, classical Opal country
Australia is the classical Opal country and today is the worldwide most important supplier of Fine Opals. Almost 95 per cent of all Opals come from Australian mines. The remaining five per cent are mined in Mexico, and in Brazil’s north, also in the US states of Idaho and Nevada, but recently the stones have also been found in Ethiopia and in the West African country of Mali.
The history of Australian Opal began actually millions of years ago, when parts of Australia were covered by a vast inland sea, and stone sediment was deposited along its shoreline. When the water masses flooded back, they flushed water containing silica into the resulting cavities and niches in the sedimentary rocks, and also the remains of plants and animals were deposited there. Slowly the silica stone transformed into Opal, for basically Opals are simply a combination of silica and water. Or, to be more precise: Opals are a gel from silica, with varying percentages of water.
In 1849 the first Opal blocks were accidentally found on an Australian cattle station called Tarravilla . the first Opal prospectors started in 1890 at White Cliff mining the Opal rocks. And even today the eyes of Opal lovers light up when somebody mentions places like White Cliffs, Lightning Ridge, Andamooka or Coober Peddy: for these are the legendary sites of the Australian Opal fields. The most famous one is probably Lightning Ridge, the place where mainly the coveted Black Opal is found. Andamooka, where Crystal Opal and Light Opal are brought to the light of day, cam boast to be the place where the probably largest Opal was found, with a weight of 6 ,843 kilograms, the “Andamooka Desert Flame”. Coober Peddy, by the way, is a word from Aborigine language meaning „white man in a hole“. This clearly describes how Opal was in fact mined: many Opal prospectors made their home in deep holes or caves in the ground, to protect themselves from the burning heat of daytime and from the icy winds of night time. Usually they worked only with tolls such as pick and shovel. Buckets full of soil, hopefully containing Opal rocks, were pulled up out of the depths of 5 to 40 m deep shafts by hand, for this is the depth of the Opal containing crevices and cavities, which are also mined nowadays.
Being an Opal prospector is still not an easy job, although today of course there are some technical means available, such as trucks or conveyor belts. And still the hope to make the find of a lifetime which will let you live happily ever after attracts many men and women to come to the hot and dusty Australian outback.
About cabochons, doublets and triplets
In order to best bring out the play of colour in a Fine Opal, the stones are cut and polished to round or oval cabochons, or any other softly domed shape , depending on the raw material. Only the best qualities of Fire Opal, however, are suited to faceting. The Opal cutter will first of all carefully remove any impurities using a diamond cutting wheel, before working out the rough basic shape. The comes the fine cutting, the finishing with sandpaper and then the final polishing with a wet leather wheel.
Opal is often found as flat lenses, or thin layers, bigger pieces are rather rare. If you leave a thin but supporting layer of the harder mother rock, you will receive a pre-stage of the Opal-doublets which are frequently used today for mass produced jewellery. These are gemstone combinations consisting of a surface from millimetre-thin Opal plates, which have been mounted on Onyx, Obsidian, artificial black glass, or Potch-Opal. Triplets have been developed from this design, here the Opal layer receives an additional cover from Rock Crystal, Plastic, Hard Glass or Lead Glass for protection.
Opal love to be worn on the skin
Due to the differing percentage of water, Opals may easily become brittle. They always contain water – usually between 2 and 6 per cent, but sometimes even more. Thus if stored too dry or exposed to heat over a longer period of time, Opals will show fissures and the play of colour will become paler. Therefore, Opal jewellery should be worn as often as possible, for then the gemstone will receive the needed humidity from the air and from the skin of its wearer.
Opals are not very hard: they only achieve 5.5 to 6 on the Mohs’ scale. Therefore they appreciate a protective setting. In earlier days Opal’s sensitive surface was often oiled, but today also sealing them with colourless artificial resin has become quite popular.
From Harlequin to Peacock: Opal experts lingo
When Opal experts talk about “harlequin”, “church windows” or “needle fire”, do not be surprised. They are probably discussing Opals. The play of colour in this stone is described with many imaginative terms for various structures and phenomena, like, for example, “flame opal”, “lightning and peacock opal”, or the above named “harlequin” and “church window”.
Opal’s value is not only determined by the body colour, transparency and factors based on place of occurrence. (Body colour refers to the basic colour of the gemstone, which can be black, dark or light and coloured). It is also important if the stone is transparent, translucent or opaque. And the opalizing effect may also influence the transparency.
Black Opal or Opal with a dark grey body shows the most brilliant play of colours imaginable. Crystal opal, which comes immediately after Black Opal in the hit list, should be more transparent with a deep play of colours. White or milky Opals show more diffuse colours and are the least expensive Opals. The occurrence-specific characteristics include, for instance, denominations such as “Black Opal from Lightning Ridge” (we are talking absolute top luxury here) or “Mexican Fire Opal”.
The most important criterion for determining the price of an Opal, however, is the play of colour, the colours as such and their pattern. If the colour red appears when looking through the stone, all the other colours will appear also. For evaluating Opals the thickness of the Opal layer is considered, the beauty of the patterning, the cut, weight and finish. Finally the total impression will be decisive, and of course offer and demand will determine ho much you will have to pay for “your” Opal. If you are interested in a really valuable specimen, get an Opal expert to advise you, because it takes a real expert to know about the many criteria which determine the price.
Opals and emotions
For ages people have been believing in the healing power of Opal. It is reported to be able to solve depressions and to help its wearer find the true and real love. Opals are supposed to further enhance the positive characteristics for people born under the zodiac sign of Cancer. Black Opal is recommended to those born under Scorpio, and Boulder Opal is the lucky stone for Aries.
*********************************************
Opal is a mineraloid gel which is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with limonite, sandstone, rhyolite, marl and basalt. The word opal comes from the Latin opalus, by Greek ὀπάλλιος opallios.
The water content is usually between three and ten percent, but can be as high as twenty percent. Opal ranges from clear through white, gray, red, orange, yellow, green, blue, magenta, rose, pink, slate, olive, brown, and black. Of these hues, the reds against black are the most rare, whereas white and greens are the most common. These color variations are a function of growth size into the red and infrared wavelengths. Opal is Australia's national gemstone.
Precious opal
Precious opal shows a variable interplay of internal colors and even though it is a mineraloid, it does have an internal structure. At micro scales precious opal is composed of silica spheres some 150 to 300 nm in diameter in a hexagonal or cubic close-packed lattice. These bordered silica spheres produce the internal colors by causing the interference and diffraction of light passing through the microstructure of the opal. It is the regularity of the sizes and the packing of these spheres that determines the quality of precious opal. Where the distance between the regularly packed planes of spheres is approximately half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from the grating created by the stacked planes. The spacing between the planes and the orientation of planes with respect to the incident light determines the colors observed. The process can be described by Bragg's Law of diffraction.
Visible light of diffracted wavelengths cannot pass through large thicknesses of the opal. This is the basis of the optical band gap in a photonic crystal, of which opal is the best known natural example. In addition, microfractures may be filled with secondary silica and form thin lamellae inside the opal during solidification. The term opalescence is commonly and erroneously used to describe this unique and beautiful phenomenon, which is correctly termed play of color. Contrarily, opalescence is correctly applied to the milky, turbid appearance of common or potch opal. Potch does not show a play of color.
The veins of opal displaying the play of color are often quite thin, and this has given rise to unusual methods of preparing the stone as a gem. An opal doublet is a thin layer of opal, backed by a swart mineral such as ironstone, basalt, or obsidian. The darker backing emphasizes the play of color, and results in a more attractive display than a lighter potch.
Combined with modern techniques of polishing, doublet opal produces similar effect of black or boulder opals at a mere fraction of the price. Doublet opal also has the added benefit of having genuine opal as the top visible and touchable layer, unlike triplet opals.
The triplet-cut opal backs the colored material with a dark backing, and then has a domed cap of clear quartz or plastic on top, which takes a high polish and acts as a protective layer for the relatively fragile opal. The top layer also acts as a magnifier, to emphasize the play of color of the opal beneath, which is often of lower quality. Triplet opals therefore have a more artificial appearance, and are not classed as precious opal.
Besides the gemstone varieties that show a play of color, there are other kinds of common opal such as the milk opal, milky bluish to greenish (which can sometimes be of gemstone quality), resin opal which is honey-yellow with a resinous luster, wood opal which is caused by the replacement of the organic material in wood with opal,menilite which is brown or grey, hyalite is a colorless glass-clear opal sometimes called Muller's Glass, geyserite, also called siliceous sinter, deposited around hot springs or geysers and diatomite or diatomaceous earth, the accumulations of diatom shells or tests.
Fire opals are transparent to translucent opals with warm body colors yellow, orange, orange-yellow or red and they do not usually show any play-of-color, although occasionally a stone will exhibit bright green flashes. The most famous source of fire opals is the state of Querétaro in Mexico and these opals are commonly called Mexican fire opals.
Peruvian opal (also called blue opal) is a semi-opaque to opaque blue-green stone found in Peru which is often cut to include the matrix in the more opaque stones. It does not display pleochroism.
Sources of opal
Australia produces around 97% of the world's opal. 90% is called ‘light opal’ or white and crystal opal. White makes up 60% of the opal productions but cannot be found in all of the opal fields. Crystal opal or pure hydrated silica makes up 30% of the opal produced, 8% is black and only 2% is boulder opal.
The town of Coober Pedy in South Australia is a major source of opal. The world's largest and most valuable gem opal “Olympic Australis” was found in August 1956 at the “Eight Mile” opal field in Coober Pedy. It weighs 17,000 carats (3450 grams) and is 11 inches long (280 mm), with a height of 4¾ inches (120 mm) and a width of 4½ inches (115 mm). It is valued at AUD$2,500,000
Andamooka in South Australia is also a major producer of matrix opal, crystal opal, and black opal. Another Australian town, Lightning Ridge in New South Wales, is the main source of black opal, opal containing a predominantly dark background (dark-gray to blue-black displaying the play of color). Boulder opal consists of concretions and fracture fillings in a dark siliceous ironstone matrix. It is found sporadically in western Queensland, from Kynuna in the north, to Yowah and Koroit in the south. The rarest type of Australian opal is "pipe" opal, closely related to boulder opal, which forms in sandstone with some iron-ore content, usually as fossilized tree roots. Its largest quantities are found around Jundah in South West Queensland.
Multi-colored rough opal specimen from Virgin Valley, Nevada, USA.
The Virgin Valley opal fields of Humboldt County in northern Nevada produce a wide variety of precious black, crystal, white, fire, and lemon opal. The black fire opal is the official gemstone of Nevada. Most of the precious opal is partial wood replacement. Miocene age opalised teeth, bones, fish, and a snake head have been found. Some of the opal has high water content and may desiccate and crack when dried. The largest black opal in the Smithsonian Institution comes from the Royal Peacock opal mine in the Virgin Valley.
Another source of white base opal or creamy opal in the United States is Spencer, Idaho.[citation needed] A high percentage of the opal found there occurs in thin layers.
Other significant deposits of precious opal around the world can be found in the Czech Republic, Slovakia, Hungary, Turkey, Indonesia, Brazil (in Pedro II, Piauí), Honduras, Guatemala, Nicaragua and Ethiopia.
In late 2008, NASA announced that it had discovered opal deposits on Mars.
Synthetic opal
As well as occurring naturally, opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974.
The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Synthetics are further distinguished from naturals by the former's lack of fluorescence under UV light. Synthetics are also generally lower in density and are often highly porous.
Two notable producers of synthetic opal are the companies Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (e.g., plastic stabilizers). The imitation opals seen in vintage jewelry are often foiled glass, glass-based "Slocum stone", or later plastic materials.
Local atomic structure of opals
The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As a mineraloid, there is no unit cell that describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order (amorphous opal) and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal.
Dehydration experiments and infrared spectroscopy have shown that most of the H2O in the formula of SiO2·nH2O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as Si-O-H, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.
The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully-corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.
Microcrystalline opal
Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny microcrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called Lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5wt%
Non-crystalline opal
Two broad categories of non-crystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.
Non-crystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure in sedimentary rocks, as some of the stacking disorder is removed.
Historical superstitions
In the Middle Ages, opal was considered a stone that could provide great luck because it was believed to possess all the virtues of each gemstone whose color was represented in the color spectrum of the opal.
It was also said to confer the power of invisibility if wrapped in a fresh bay leaf and held in the hand.
Following the publication of Sir Walter Scott's Anne of Geierstein in 1829, however, opal acquired a less auspicious reputation. In Scott's novel, the Baroness of Arnheim wears an opal talisman with supernatural powers. When a drop of holy water falls on the talisman, the opal turns into a colorless stone and the Baroness dies soon thereafter. Due to the popularity of Scott's novel, people began to associate opals with bad luck and death.
Even as recently as the beginning of the 20th century, it was believed that when a Russian saw an opal among other goods offered for sale, he or she should not buy anything more since the opal was believed to embody the evil eye.
Opal is considered the birthstone for people born in October or under the sign of Libra.
Opal is a mineraloid gel which is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with limonite, sandstone, rhyolite, marl and basalt. The word opal comes from the Latin opalus, by Greek ὀπάλλιος opallios.
The water content is usually between three and ten percent, but can be as high as twenty percent. Opal ranges from clear through white, gray, red, orange, yellow, green, blue, magenta, rose, pink, slate, olive, brown, and black. Of these hues, the reds against black are the most rare, whereas white and greens are the most common. These color variations are a function of growth size into the red and infrared wavelengths. Opal is Australia's national gemstone.
Precious opal
Precious opal shows a variable interplay of internal colors and even though it is a mineraloid, it does have an internal structure. At micro scales precious opal is composed of silica spheres some 150 to 300 nm in diameter in a hexagonal or cubic close-packed lattice. These bordered silica spheres produce the internal colors by causing the interference and diffraction of light passing through the microstructure of the opal. It is the regularity of the sizes and the packing of these spheres that determines the quality of precious opal. Where the distance between the regularly packed planes of spheres is approximately half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from the grating created by the stacked planes. The spacing between the planes and the orientation of planes with respect to the incident light determines the colors observed. The process can be described by Bragg's Law of diffraction.
The veins of opal displaying the play of color are often quite thin, and this has given rise to unusual methods of preparing the stone as a gem. An opal doublet is a thin layer of opal, backed by a swart mineral such as ironstone, basalt, or obsidian. The darker backing emphasizes the play of color, and results in a more attractive display than a lighter potch.
Combined with modern techniques of polishing, doublet opal produces similar effect of black or boulder opals at a mere fraction of the price. Doublet opal also has the added benefit of having genuine opal as the top visible and touchable layer, unlike triplet opals.
The triplet-cut opal backs the colored material with a dark backing, and then has a domed cap of clear quartz or plastic on top, which takes a high polish and acts as a protective layer for the relatively fragile opal. The top layer also acts as a magnifier, to emphasize the play of color of the opal beneath, which is often of lower quality. Triplet opals therefore have a more artificial appearance, and are not classed as precious opal.
Besides the gemstone varieties that show a play of color, there are other kinds of common opal such as the milk opal, milky bluish to greenish (which can sometimes be of gemstone quality), resin opal which is honey-yellow with a resinous luster, wood opal which is caused by the replacement of the organic material in wood with opal,menilite which is brown or grey, hyalite is a colorless glass-clear opal sometimes called Muller's Glass, geyserite, also called siliceous sinter, deposited around hot springs or geysers and diatomite or diatomaceous earth, the accumulations of diatom shells or tests.
Fire opals are transparent to translucent opals with warm body colors yellow, orange, orange-yellow or red and they do not usually show any play-of-color, although occasionally a stone will exhibit bright green flashes. The most famous source of fire opals is the state of Querétaro in Mexico and these opals are commonly called Mexican fire opals.
Peruvian opal (also called blue opal) is a semi-opaque to opaque blue-green stone found in Peru which is often cut to include the matrix in the more opaque stones. It does not display pleochroism.
Sources of opal
Australia produces around 97% of the world's opal. 90% is called ‘light opal’ or white and crystal opal. White makes up 60% of the opal productions but cannot be found in all of the opal fields. Crystal opal or pure hydrated silica makes up 30% of the opal produced, 8% is black and only 2% is boulder opal.
The town of Coober Pedy in South Australia is a major source of opal. The world's largest and most valuable gem opal “Olympic Australis” was found in August 1956 at the “Eight Mile” opal field in Coober Pedy. It weighs 17,000 carats (3450 grams) and is 11 inches long (280 mm), with a height of 4¾ inches (120 mm) and a width of 4½ inches (115 mm). It is valued at AUD$2,500,000
Andamooka in South Australia is also a major producer of matrix opal, crystal opal, and black opal. Another Australian town, Lightning Ridge in New South Wales, is the main source of black opal, opal containing a predominantly dark background (dark-gray to blue-black displaying the play of color). Boulder opal consists of concretions and fracture fillings in a dark siliceous ironstone matrix. It is found sporadically in western Queensland, from Kynuna in the north, to Yowah and Koroit in the south. The rarest type of Australian opal is "pipe" opal, closely related to boulder opal, which forms in sandstone with some iron-ore content, usually as fossilized tree roots. Its largest quantities are found around Jundah in South West Queensland.
Multi-colored rough opal specimen from Virgin Valley, Nevada, USA.
The Virgin Valley opal fields of Humboldt County in northern Nevada produce a wide variety of precious black, crystal, white, fire, and lemon opal. The black fire opal is the official gemstone of Nevada. Most of the precious opal is partial wood replacement. Miocene age opalised teeth, bones, fish, and a snake head have been found. Some of the opal has high water content and may desiccate and crack when dried. The largest black opal in the Smithsonian Institution comes from the Royal Peacock opal mine in the Virgin Valley.
Another source of white base opal or creamy opal in the United States is Spencer, Idaho.[citation needed] A high percentage of the opal found there occurs in thin layers.
Other significant deposits of precious opal around the world can be found in the Czech Republic, Slovakia, Hungary, Turkey, Indonesia, Brazil (in Pedro II, Piauí), Honduras, Guatemala, Nicaragua and Ethiopia.
In late 2008, NASA announced that it had discovered opal deposits on Mars.
Synthetic opal
As well as occurring naturally, opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974.
The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Synthetics are further distinguished from naturals by the former's lack of fluorescence under UV light. Synthetics are also generally lower in density and are often highly porous.
Two notable producers of synthetic opal are the companies Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (e.g., plastic stabilizers). The imitation opals seen in vintage jewelry are often foiled glass, glass-based "Slocum stone", or later plastic materials.
Local atomic structure of opals
The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As a mineraloid, there is no unit cell that describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order (amorphous opal) and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal.
Dehydration experiments and infrared spectroscopy have shown that most of the H2O in the formula of SiO2·nH2O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as Si-O-H, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.
The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully-corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.
Microcrystalline opal
Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny microcrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called Lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5wt%
Non-crystalline opal
Two broad categories of non-crystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.
Non-crystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure in sedimentary rocks, as some of the stacking disorder is removed.
Historical superstitions
In the Middle Ages, opal was considered a stone that could provide great luck because it was believed to possess all the virtues of each gemstone whose color was represented in the color spectrum of the opal.
It was also said to confer the power of invisibility if wrapped in a fresh bay leaf and held in the hand.
Following the publication of Sir Walter Scott's Anne of Geierstein in 1829, however, opal acquired a less auspicious reputation. In Scott's novel, the Baroness of Arnheim wears an opal talisman with supernatural powers. When a drop of holy water falls on the talisman, the opal turns into a colorless stone and the Baroness dies soon thereafter. Due to the popularity of Scott's novel, people began to associate opals with bad luck and death.
Even as recently as the beginning of the 20th century, it was believed that when a Russian saw an opal among other goods offered for sale, he or she should not buy anything more since the opal was believed to embody the evil eye.
Opal is considered the birthstone for people born in October or under the sign of Libra.
From Wikipedia, the free encyclopedia
